Critical exponents of the dielectric constants in diffused-phase-transition crystals

Abstract The critical exponent γ in the relation between the dielectric constant and temperature (1/ε—1/εm = C'-1x (T—Tm)γ) has been determined precisely for relaxor ferroelectrlics Pb(Mg1/3Nb2/3)O3, Pb(Zn1/3 Nb2/3)O3 and a related solid solution 0.88Pb (Zn1/3 Nb2/3)O3-0. I2PbT103, as well as for normal ferroelectrics BaTiO3 and K(Ta0. 55Nb0.45)O3. A high correlation of the γ value with the plase transition diffuseness has been found empirically. Moreover, this γ value is very close to another critical exponent γ* which is defined in the relation between the dielectric constant and hydrostatic pressure (1/ε—1/εm = C* (p—pm)γ*)