A Neutral Trinuclear Molybdenum-Sulfur(Oxygen) Cluster Complex with [Mo3(μ3-S)(μ-O)3] Core

Abstract A neutral molybdenum cluster Mo3(μ3-S)(μ-O)3(DTP)4(H2O) (DTP=diethyl dithiophosphate) is rationally synthesized and structurally characterized. Its molecules are linked via hydrogen bonding and supramolecular interactions, leading to an infinite one-dimensional chain structure.