吸附
亚甲蓝
水溶液
朗缪尔吸附模型
化学
壳聚糖
核化学
热重分析
解吸
化学吸附
自愈水凝胶
化学工程
材料科学
高分子化学
有机化学
光催化
催化作用
工程类
作者
Roshni D. Hingrajiya,Manish P. Patel
标识
DOI:10.1016/j.ijbiomac.2023.125251
摘要
The present research comprises the fabrication of magnetic Fe3O4 incorporated chitosan grafted acrylamide and N-vinylimidazole composite hydrogels (CANFe-1 to CANFe-7) via water mediated free radical polymerization technique using ammonium persulfate/tetramethyl ethylenediamine as initiator. The prepared magnetic composite hydrogel was characterized by FT-IR, TGA, SEM, XRD, and VSM analysis. A swelling study was performed to understand the swelling behavior and found CANFe-4 to be more efficient with maximum swelling hence entire removal studies were performed with CANFe-4. pHPZC analysis was performed to determine pH sensitive adsorptive removal of cationic dye (methylene blue). pH dependent adsorption of methylene blue was dominant at pH = 8 with a maximum adsorption capacity of 860 mg/g. After the adsorptive removal of methylene blue from aqueous media, a composite hydrogel can conveniently be separated from the solution with the use of an external magnet. Adsorption of methylene blue is well explained with the Langmuir adsorption isotherm and Pseudo-Second-Order kinetic model that validates chemisorption. Moreover, it was found that CANFe-4 could be frequently applied for the adsorptive removal of methylene blue for 5 consecutive adsorption-desorption cycles with 92.4 % removal efficiency. Hence, CANFe-4 offers a promising recyclable, sustainable, robust, and efficient adsorbent for wastewater treatment.
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