色素敏化染料
光电流
材料科学
能量转换效率
光敏剂
电解质
开路电压
接受者
电子受体
光化学
光电子学
化学工程
电压
电极
化学
物理化学
工程类
物理
量子力学
凝聚态物理
作者
Anna Grobelny,Zhongjin Shen,Felix T. Eickemeyer,Naura F Antariksa,Szczepan Zapotoczny,Shaik M. Zakeeruddin,Michaël Grätzel
标识
DOI:10.1002/adma.202207785
摘要
Photosensitizers yielding superior photocurrents are crucial for copper-electrolyte-based highly efficient dye-sensitized solar cells (DSCs). Herein, two molecularly tailored organic sensitizers are presented, coded ZS4 and ZS5, through judiciously employing dithieno[3,2-b:2″,3″-d]pyrrole (DTP) as the π-linker and hexyloxy-substituted diphenylquinoxaline (HPQ) or naphthalene-fused-quinoxaline (NFQ) as the auxiliary electron-accepting unit, respectively. Endowed with the HPQ acceptor, ZS4 shows more efficient electron injection and charge collection based on substantially reduced interfacial charge recombination as compared to ZS5. As a result, ZS4-based DSCs achieve a power conversion efficiency (PCE) of 13.2% under standard AM1.5G sunlight, with a high short-circuit photocurrent density (Jsc ) of 16.3 mA cm-2 , an open-circuit voltage (Voc ) of 1.05 V and a fill factor (FF) of 77.1%. Remarkably, DSCs sensitized with ZS4 exhibit an outstanding stability, retaining 95% of their initial PCE under continuous light soaking for 1000 h. It is believed that this is a new record efficiency reported so far for copper-electrolyte-based DSCs using a single sensitizer. The work highlights the importance of developing molecularly tailored photosensitizers for highly efficient DSCs with copper electrolyte.
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