Action at a distance: organic cation induced long range organization of interfacial water enhances hydrogen evolution and oxidation kinetics

spectroscopic investigations, we propose that the structure-making ability of bulky hydrophobic cations promotes the formation of hydrogen-bonded water chains connecting the electrode surface to the bulk electrolyte. In alkaline electrolytes, the HOR/HER involve the activation of interfacial water by donating or abstracting protons. The structural diffusion mechanism of protons in aqueous electrolytes enables water molecules and cations located at a distance from the electrode to influence surface-mediated reactions. The findings reported in this work highlight the prospect of leveraging the nonlocal mechanism to enhance electrocatalytic performance.