Chemically Recyclable Poly(tetrathioorthocarbonate)s: Combining High Refractive Index and Abbe Number

of 40.9, and optical transparency of 90%. Density functional theory calculations of the copolymerization process suggest that the high selectivity of poly(tetrathioorthocarbonate)s (PTOCs) originates from the thermodynamically unfavorable elimination of trithiocarbonate anions. In particular, PTOCs can be recycled to the original thiiranes and cyclic trithiocarbonates via spiro intermediates by simple pyrolysis.