ZIF-8-derived Zn, N-codoped porous carbon as a high-performance piezocatalyst for organic pollutant degradation and hydrogen production

The development of highly efficient piezocatalysts has attracted widespread attention for energy conversion and pollution abatement. This paper reports for the first time exceptional piezocatalytic properties of a Zn- and N-codoped porous carbon piezocatalyst (Zn-Nx-C) derived from the zeolitic imidazolium framework-8 (ZIF-8) for both hydrogen production and degradation of organic dyes. The Zn-Nx-C catalyst has a high specific surface area of 810.6 m2/g and retains the dodecahedron structure of ZIF-8. Under ultrasonic vibration, the hydrogen production rate of Zn-Nx-C has achieved 6.29 mmol/g/h, surpassing most recently reported piezocatalysts. Additionally, the Zn-Nx-C catalyst demonstrates a 94% degradation efficiency for organic rhodamine B (RhB) dye during 180 min of ultrasonic vibration. This work sheds new light on the potential of ZIF-based materials in the field of piezocatalysis and provides a promising avenue for future developments in the area.