塔菲尔方程
催化作用
阳极
析氧
X射线光电子能谱
镍
化学工程
材料科学
电流密度
化学
无机化学
电极
冶金
电化学
物理化学
有机化学
物理
量子力学
工程类
作者
Pingping Tan,Yuanke Wu,Yangyang Tan,Yang Xiang,Liyuan Zhou,Ning Han,Yinzhu Jiang,Shu‐Juan Bao,Xuan Zhang
出处
期刊:Small
[Wiley]
日期:2023-12-27
被引量:2
标识
DOI:10.1002/smll.202308371
摘要
By increasing the content of Ni3+ , the catalytic activity of nickel-based catalysts for the oxygen evolution reaction (OER), which is still problematic with current synthesis routes, can be increased. Herein, a Ni3+ -rich of Ni3 S4 /FeS on FeNi Foam (Ni3 S4 /FeS@FNF) via anodic electrodeposition to direct obtain high valence metal ions for OER catalyst is presented. XPS showed that the introduction of Fe not only further increased the Ni3+ concentration in Ni3 S4 /FeS to 95.02%, but also inhibited the dissolution of NiOOH by up to seven times. Furthermore, the OER kinetics is enhanced by the combination of the inner Ni3 S4 /FeS heterostructures and the electrochemically induced surface layers of oxides/hydroxides. Ni3 S4 /FeS@FNF shows the most excellent OER activity with a low Tafel slope of 11.2 mV dec-1 and overpotentials of 196 and 445 mV at current densities of 10 and 1400 mA cm-2 , respectively. Furthermore, the Ni3 S4 /FeS@FNF catalyst can be operated stably at 1500 mA cm-2 for 200 h without significant performance degradation. In conclusion, this work has significantly increased the high activity Ni3+ content in nickel-based OER electrocatalysts through an anodic electrodeposition strategy. The preparation process is time-saving and mature, which is expected to be applied in large-scale industrialization.
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