废水
环境科学
超临界流体
余热
制氢
工艺工程
温室气体
原材料
产量(工程)
水分
废物管理
氢
材料科学
环境工程
化学
热交换器
生物
生态学
物理
有机化学
工程类
冶金
复合材料
热力学
作者
Zhike Peng,Le Wang,Lei Yi,Jialing Xu,Zhigang Liu,Hui Jin,Bin Chen,Liejin Guo
标识
DOI:10.1016/j.ijhydene.2023.11.315
摘要
Oilfield wastewater with high moisture content can be efficiently treated by supercritical water gasification (SCWG) technology to produce hydrogen. This paper conducted a thermodynamic and environmental analysis of the oilfield wastewater SCWG system to provide optimization strategies. The waste heat utilization technology can enhance the heat integration of the system to reduce the exergy destruction and increase the H2 yield. Sensitivity analysis showed that a ratio of preheating water to emulsion 3 can promote water-sensitive reactions to produce H2 and save the H2 needed to maintain the energetically self-sufficient system. Low system pressures, high feedstock preheating temperatures, and low oxidation reactor temperatures can reduce system energy destruction to obtain high H2 yield and system efficiency. Meantime, the developed SCWG system has the potential to achieve natural enrichment of greenhouse gases after the H2 separation has been completed. The use of waste heat utilization technology and carbon capture and storage (CCS) technology is expected to increase system efficiency to 53.43 % and reduce global warming potential (GWP) of 5.52 kg CO2-eq/kg H2. This work would be of great value to the process design and optimization for the SCWG system of oilfield wastewater.
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