Longitudinally Grafting of Graphene with Iron Phthalocyanine‐based Porous Organic Polymer to Boost Oxygen Electroreduction

Iron phthalocyanine-based polymers (PFePc) are attractive noble-metal-free candidates for catalyzing oxygen reduction reaction (ORR). However, the low site-exposure degree and poor electrical conductivity of bulk PFePc restricted their practical applications. Herein, laminar PFePc nanosheets covalently and longitudinally linked to graphene (3D-G-PFePc) was prepared. Such structural engineering qualifies 3D-G-PFePc with high site utilization and rapid mass transfer. Thence, 3D-G-PFePc demonstrates efficient ORR performance with a high specific activity of 69.31 μA cm^-2 , a high mass activity of 81.88 A g^-1 , and a high turnover frequency of 0.93 e s^-1 site^-1 at 0.90 V vs. reversible hydrogen electrode in O₂ -saturated 0.1 M KOH, outperforming the lamellar PFePc wrapped graphene counterpart. Systematic electrochemical analyses integrating variable-frequency square wave voltammetry and in situ scanning electrochemical microscopy further underline the rapid kinetics of 3D-G-PFePc towards ORR.