结晶
材料科学
有机太阳能电池
涂层
能量转换效率
活动层
光电子学
混溶性
聚合物太阳能电池
光伏系统
化学工程
图层(电子)
纳米技术
复合材料
电气工程
聚合物
薄膜晶体管
工程类
作者
Anran Wang,Yifei Kang,Cheng-Hao Hou,Rong Li,Yilong Song,Qingfeng Dong
标识
DOI:10.1016/j.scib.2023.05.005
摘要
The miscibility between active layer donors (D) and acceptors (A) is a key factor impeding the development of organic photovoltaics (OPVs) toward higher performance and large-area production. In this study, melt blending crystallization (MBC) was used to accomplish molecular-level blending and highly oriented crystallization in bulk heterojunction (BHJ) films realized by a scalable blade coating process, which increased the D/A contact area and provided sufficient exciton diffusion and dissociation. At the same time, the highly organized and balanced crystalline nanodomain structures permitted dissociated carriers to be efficiently transmitted and collected, resulting in significantly enhanced short-circuit current density, fill factor, and efficiency of the device by means of optimum melting temperature and quenching rates. The method can be simply incorporated into current efficient OPV material systems and achieve a device performance comparable to the best values. The blade-coating-processed PM6/IT-4F MBC devices achieved an efficiency of 13.86% in a small-area device and 11.48% in a large-area device. A power conversion efficiency (PCE) of 17.17% was obtained in PM6:BTP-BO-4F devices, and a PCE of 16.14% was acquired in PM6:Y6 devices.
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