Mechanoelectrical metamaterials for broad-range, high-sensitivity pressure sensing

Mechanical metamaterials exploit precise control of unit-cell geometry and their macroscopic organization to realize unusual properties. Expanding the capabilities of mechanical metamaterials to incorporate additional functionality remains a challenge. We describe 3D-printed metamaterials embedded with molecular ferroelectrics for use as self-powered pressure sensors. Our gradient lattice design allows for adaptive reconfiguration and controlled deformation-mode transitions, yielding a synergy of low modulus and high load-bearing capacity alongside a monotonic mechanical load-electrical signal response. Furthermore, we implement a modulus gradient in the metamaterials to enhance sensitivity in low-loading regions and extend the detection range across six orders of magnitude. With a combination of high sensitivity and broad detection range, the dual-gradient metamaterials overcome the limitations imposed by the inverse relationships in existing sensors.