Synthesis, Spectral Studies and Theoretical Treatment of New Au (III) and Cu(II) Complexes of Bidenetate Ligands 2-Benzamido Benzothiazole, and 2-Actamido Benzothiazole.

The Schiff base ligand [2,3,8,9-tetra -methyl-1,4,5,7,10,12-hexa azo-5,12-dihydro -6,11-dione 1,3,7,10-dudec-tetra-ene] [H2L] and its complexes with ( Co (II) , Ni (II) and Pd (II) ) was prepared in two steps. In the first a solution of (2,5-Hexandion) in methanol react under reflux with (semicarbazidhydrochlorid) in 1:2 mole ratio to give an intermediate compound [2,5-Hexandion bis (Semicarbazone)] which react in the second step with another mole of ( 2,5-Hexandion) giving the mentioned ligand. The complexes were then synthesized by direct reaction of the corresponding metal chloride with the ligand. The ligand and complexes have been characterized by spectroscopic methods [IR, (UV-Vis), HPLC and (A.A)], chloride content and conductivity measuremenst. The data of these measurements suggest a square planar geometry around Ni (II) and Pd (II) ions and a tetrahedral geometry around Co (II) ion.