材料科学
微观结构
合金
纳米尺度
相(物质)
复合数
脆性
复合材料
冶金
纳米技术
化学
有机化学
作者
He Xi,W.Q. Ming,Yutao He,Pan Xie,Xinxin Xu,Zhiyuan Zhang,J.H. Chen
标识
DOI:10.1016/j.jallcom.2022.164238
摘要
Embedded nanoscale Al particles are promising for improving the toughness of large eutectic Si-phase particles in Al-Si-based alloys. However, the composition and fine structure of such Al particles in Al-Si alloys with Cu addition remain poorly known. Here, through advanced aberration-corrected transmission electron microscopy and electron tomography, we reveal that the void-free particles are composed of a pure Al phase (face-centered cubic structure) and an AlCu phase with three types of crystallographic orientation relationships. The AlCu phase, which possesses a lattice constant of a = 0.300 nm and the space group of Pm3̅m, grows at the interface between Al and Si phases. Our study suggests that these Al(Cu) composite particles are directly solidified from the melt during solidification, rather than indirectly precipitated from a Si-Al-Cu solid solution. Heterogeneous nucleation of the AlCu phase on Si surface planes plays a critical role in forming these Al(Cu) particles embedded inside the large brittle Si particles.
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