Synthesis of unsymmetrical 1,3-substituted-1,3-dihydro-benzimidazolones via copper-catalyzed C–N coupling under visible light

Although photoinduced copper catalysis for carbon–nitrogen (C–N) amine bond formation with alkyl/aryl halides has been developed, the potential of copper photocatalysis for the synthesis of 1,3-substituted benzimidazolones remains mostly unexplored.