Recent Advances of Polymeric Membranes in Tackling Plasticization and Aging for Practical Industrial CO2/CH4 Applications—A Review

Membranes are a promising technology for bulk CO₂ separation from natural gas mixtures due to their numerous advantages. Despite the numerous fundamental studies on creating better quality membrane efficiency, scaling up the research work for field testing requires huge efforts. The challenge is to ensure the stability of the membrane throughout the operation while maintaining its high performance. This review addresses the key challenges in the application of polymeric technology for CO₂ separation, focusing on plasticization and aging. A brief introduction to the properties and limitations of the current commercial polymeric membrane is first deliberated. The effect of each plasticizer component in natural gas towards membrane performance and the relationship between operating conditions and the membrane efficiency are discussed in this review. The recent technological advancements and techniques to overcome the plasticization and aging issues covering polymer modification, high free-volume polymers, polymer blending and facilitated transport membranes (FTMs) have been highlighted. We also give our perspectives on a few main features of research related to polymeric membranes and the way forwards. Upcoming research must emphasize mixed gas with CO₂ including minor condensable contaminants as per real natural gas, to determine the competitive sorption effect on CO₂ permeability and membrane selectivity. The effects of pore blocking, plasticization and aging should be given particular attention to cater for large-scale applications.