Bioinspired Graphene Aerogels with Hybrid Wettability for Solar-Driven Purification of Complex Wastewater

Salt deposition and pollutant enrichment greatly hamper efficient and sustainable water production for a solar evaporator. Inspired by the desert beetle, a dual-region hydrophobic graphene/hydrophilic titanium dioxide (TiO2) aerogel (GTA) with internal hydrophilic–hydrophobic hybrid wettability structure is prepared via a facile freeze-drying and thermal reduction method. The evaporator shows adjustable wettability, optimized water content, and a low energy loss in the evaporation process. Simultaneously, the hybrid wetting structure in aerogel subjects salt to a dynamic crystallization–dissolution process to prevent salt deposition. The GTA solar evaporator achieves an evaporation rate of 1.52 kg·m–2·h–1 with a 91.02% efficiency under 1 sun irradiation. Furthermore, GTAs achieve a stable evaporation rate in high salinity brine (25 wt % NaCl) under 1 sun irradiation for 100 h, which could compete well with other most advanced photothermal evaporation materials. Moreover, the synergistic effect of graphene and TiO2 endows GTAs with excellent photocatalytic degradation and self-cleaning properties, which can effectively reduce the enrichment of contaminants on the evaporator. Therefore, GTA evaporators can efficiently and stably obtain clean water from seawater and wastewater, which provides a feasible strategy for the purification of complex wastewater.