Dominant orbital magnetization in the prototypical altermagnet MnTe

Altermagnetism is an unconventional form of antiferromagnetism characterized by momentum-dependent spin polarization of electronic states and zero net magnetization, arising from specific crystalline symmetries. In the presence of spin-orbit coupling (SOC) and broken time-reversal symmetry, altermagnets can exhibit finite net magnetization and anomalous Hall effect (AHE), phenomena typically associated with ferromagnets. Due to the dependence of AHE on magnetization, understanding the interplay between spin and orbital contributions to magnetization is essential for interpreting experiments and designing altermagnetic devices. In this work, we use density functional theory to investigate the intrinsic spin and orbital magnetization of the magnetic ground state of the prototypical altermagnet α-MnTe. We find that SOC induces weak ferromagnetism through spin canting, accompanied by a slight in-plane rotation of the Néel vector. Notably, we identify a significant net orbital magnetization of 0.176 μB per unit cell oriented along the z-axis, while the spin magnetization in the same direction is much smaller at 0.002 μB. By varying the chemical potential, we show that the spin magnetization is tunable through hole doping, whereas the orbital magnetization remains robust against carrier density changes. These results highlight the important role of orbital magnetization and establish its relevance for orbital-based phenomena in altermagnets.