Syntheses and Coordination Chemistry of Thiosemicarbazone-based Titanium Complexes

Two routes leading to thiosemicarbazone-based complexes are reported with the view of developing ionic titanium complexes as cytotoxic metallodrugs. The reaction of bis(π-η 5 :σ-η 1 -pentafulvene)titanium complexes with most thiosemicarbazones gives κ 2 N , S thiosemicarbazonido...