阳极
量子点
石墨烯
材料科学
钾
钾离子电池
电池(电)
色散(光学)
电化学
石墨烯量子点
硫化锌
硫化物
纳米技术
化学工程
电极
离子
锌
化学
冶金
功率(物理)
物理化学
有机化学
工程类
物理
光学
磷酸钒锂电池
量子力学
作者
Yaqin Qi,Yong Yang,Qian Hou,Kun Zhang,Hui Zhao,Haijun Su,Lijiao Zhou,Xingrui Liu,Chao Shen,Keyu Xie
标识
DOI:10.1016/j.cclet.2020.08.030
摘要
The potassium-ion batteries (PIBs) have become the promising energy storage devices due to their relatively moderate cost and plenteous potassium resources. Whereas, the main drawback of PIBs is unsatisfactory electrochemical performance induced by the larger ionic radius of potassium ion. Herein, we report a well-designed, uniform-dispersed, and morphology-controllable zinc sulfide (ZnS) quantum dots loading on graphene as an anode in the PIBs. The directed uniform dispersion of the in-situ growing ZnS quantum dots (∼2.8 nm in size) on graphene can mitigate the volume effect during the insertion-extraction process and shorten the migration path of potassium ions. As a result, the battery exhibits superior cycling stability (350.4 mAh/g over 200 cycles at 0.1 A/g) and rate performance (98.8 mAh/g at 2.0 A/g). We believe the design of active material with quantum dot-minimized size provides a novel route into PIBs and contributes to eliminating the major electrode failure issues of the system.
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