材料科学
储能
电池(电)
电解质
阳极
纳米技术
锂(药物)
有机自由基电池
电化学
插层(化学)
铝
工艺工程
电极
无机化学
冶金
工程类
内分泌学
物理化学
功率(物理)
化学
物理
医学
量子力学
作者
Giuseppe Antonio Elia,Krystan Marquardt,Katrin Hoeppner,Sébastien Fantini,Rongying Lin,Etienne Knipping,Willi Peters,Jean‐François Drillet,Stefano Passerini,Robert W. Hahn
标识
DOI:10.1002/adma.201601357
摘要
A critical overview of the latest developments in the aluminum battery technologies is reported. The substitution of lithium with alternative metal anodes characterized by lower cost and higher abundance is nowadays one of the most widely explored paths to reduce the cost of electrochemical storage systems and enable long‐term sustainability. Aluminum based secondary batteries could be a viable alternative to the present Li‐ion technology because of their high volumetric capacity (8040 mAh cm −3 for Al vs 2046 mAh cm −3 for Li). Additionally, the low cost aluminum makes these batteries appealing for large‐scale electrical energy storage. Here, we describe the evolution of the various aluminum systems, starting from those based on aqueous electrolytes to, in more details, those based on non‐aqueous electrolytes. Particular attention has been dedicated to the latest development of electrolytic media characterized by low reactivity towards other cell components. The attention is then focused on electrode materials enabling the reversible aluminum intercalation‐deintercalation process. Finally, we touch on the topic of high‐capacity aluminum‐sulfur batteries, attempting to forecast their chances to reach the status of practical energy storage systems.
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