Breathable and skin-conformal electronic skin with dual-modality synchronous perception of pressure and temperature

Abstract The random nanofiber distribution in traditional electrospun membranes restricts the pressure sensing sensitivity and measurement range of electronic skin. Moreover, current multimodal sensing suffers from issues like overlapping signal outputs and slow response. Herein, a novel electrospinning method is proposed to prepare double-coupled microstructured nanofibrous membranes. Through the effect of high voltage electrostatic field in the electrospinning, the positively charged nanofibers are preferentially attached to the negatively charged foam surface, forming the ordered two-dimensional honeycomb porous nanofibrous membrane with three-dimensional spinous microstructure. Compared with the conventional random porous nanofibrous membrane, the bionic two-dimensional honeycomb and three-dimensional spinous dual-coupled microstructures in the ordered porous nanofibrous membrane endows the electronic skin with significantly improved mechanical properties (maximum tensile strain increased by 77% and fatigue resistance increased by 35%), air permeability (water vapor transmission rate increased by 16%) and sensing properties (pressure sensitivity increased by 276% and detection range increased by 137%). Furthermore, the electronic skin was constructed by means of a conformal composite ionic liquid functionalized nanofibrous membrane, and the real-time and interference-free dual-signal monitoring of pressure and temperature (maximum temperature coefficient of resistance: −0.918 °C −1 ) was realized.