压电
纳米-
纳米颗粒
纳米材料
材料科学
铁电性
应变工程
分解水
多孔性
钙钛矿(结构)
纳米技术
拉伤
化学工程
催化作用
复合材料
光电子学
化学
有机化学
内科学
医学
光催化
硅
电介质
工程类
作者
Ran Su,Zhipeng Wang,Lina Zhu,Ying Pan,Dawei Zhang,Hui Wen,Zheng‐Dong Luo,Linglong Li,Fa-tang Li,Ming Wu,Liqiang He,Pankaj Sharma,Jan Seidel
标识
DOI:10.1002/anie.202103112
摘要
Abstract Developing nano‐ferroelectric materials with excellent piezoelectric performance for piezocatalysts used in water splitting is highly desired but also challenging, especially with respect to reaching large piezo‐potentials that fully align with required redox levels. Herein, heteroepitaxial strain in BaTiO 3 nanoparticles with a designed porous structure is successfully induced by engineering their surface reconstruction to dramatically enhance their piezoelectricity. The strain coherence can be maintained throughout the nanoparticle bulk, resulting in a significant increase of the BaTiO 3 tetragonality and thus its piezoelectricity. Benefiting from high piezoelectricity, the as‐synthesized blue‐colored BaTiO 3 nanoparticles possess a superb overall water‐splitting activity, with H 2 production rates of 159 μmol g −1 h −1 , which is almost 130 times higher than that of the pristine BaTiO 3 nanoparticles. Thus, this work provides a generic approach for designing highly efficient piezoelectric nanomaterials by strain engineering that can be further extended to various other perovskite oxides, including SrTiO 3 , thereby enhancing their potential for piezoelectric catalysis.
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