ChemInform Abstract: Chemistry of Organosilicon Compounds. Part 254. Stereohomogeneous Synthesis of E‐ and Z‐Crotyltrifluorosilanes and Highly Stereoselective Allylation of Aldehydes.
Abstract The synthesis of the isomeric trifluorosilyl‐2‐butenes Z‐(IV) and E‐(VII) from butadiene (I) or from trans‐2‐butenyl chloride (V) is described.