An Unfused‐Core‐Based Nonfullerene Acceptor Enables High‐Efficiency Organic Solar Cells with Excellent Morphological Stability at High Temperatures

Most nonfullerene acceptors developed so far for high-performance organic solar cells (OSCs) are designed in planar molecular geometry containing a fused-ring core. In this work, a new nonfullerene acceptor of DF-PCIC is synthesized with an unfused-ring core containing two cyclopentadithiophene (CPDT) moieties and one 2,5-difluorobenzene (DFB) group. A nearly planar geometry is realized through the F···H noncovalent interaction between CPDT and DFB for DF-PCIC. After proper optimizations, the OSCs with DF-PCIC as the acceptor and the polymer PBDB-T as the donor yield the best power conversion efficiency (PCE) of 10.14% with a high fill factor of 0.72. To the best of our knowledge, this efficiency is among the highest values for the OSCs with nonfullerene acceptors owning unfused-ring cores. Furthermore, no obvious morphological changes are observed for the thermally treated PBDB-T:DF-PCIC blended films, and the relevant devices can keep ≈70% of the original PCEs upon thermal treatment at 180 °C for 12 h. This tolerance of such a high temperature for so long time is rarely reported for fullerene-free OSCs, which might be due to the unique unfused-ring core of DF-PCIC. Therefore, the work provides new idea for the design of new nonfullerene acceptors applicable in commercial OSCs in the future.