三吡啶
化学
噻吩
戒指(化学)
硼酸
乙炔
铃木反应
衍生工具(金融)
产量(工程)
高分子化学
组合化学
药物化学
有机化学
钯
催化作用
金属
冶金
材料科学
经济
金融经济学
作者
Paul Hommes,Hans‐Ulrich Reißig
标识
DOI:10.1002/ajoc.201600215
摘要
Abstract New 2,2′:6′,2′′‐terpyridine derivatives were prepared by Suzuki–Miyaura coupling of the corresponding 4,4′′‐bis(nonaflate) with the appropriate boronic acid derivatives. The corresponding 4,4′′‐diazido terpyridine derivative allowed a copper(I)‐promoted click reaction with phenyl acetylene to provide the bis(triazolyl)‐substituted terpyridine in excellent yield. For comparison, analogs or terpyridines with a central thiophene ring were synthesized by applying the well proven cyclocondensation reaction of the bis(β‐ketoenamide) derived from 2,5‐thiophenedicarboxylic acid. The UV/Vis spectra as well as the fluorescence spectra of these new compounds were recorded and compared with related heterocycles.
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