检出限
Mercury(编程语言)
纳米颗粒
水溶液
催化作用
选择性
线性范围
化学
多孔性
电化学
纳米技术
化学工程
材料科学
色谱法
电极
有机化学
计算机科学
物理化学
工程类
程序设计语言
作者
Jiaojiao Zhou,Weijia Zhu,Xuqin Lv,Xiaoping Du,Jiangling He,Jie Cai
出处
期刊:ACS applied nano materials
[American Chemical Society]
日期:2022-11-23
卷期号:5 (12): 18885-18893
被引量:10
标识
DOI:10.1021/acsanm.2c04662
摘要
Mercury ion (Hg2+) is toxic and can severely damage the environment and human health. Therefore, sensitive and selective Hg2+ detection methods are needed. Here, we synthesized dendritic silica nanospheres (DSN) with central-radial porous structures and immobilized Au and Pt nanoparticles into their pores. The synthesized DSN with Au and Pt nanoparticles (AuPt@DSN) exhibited superior peroxidase-like activity, stability, and dispersibility. We found that AuPt@DSN can specifically reduce Hg2+, leading to the decreased catalytic activity of the nanozymes. Under optimal testing conditions, the AuPt@DSN material was efficiently used for the visual detection of Hg2+. The detection limit was 8.58 pM with a linear range from 0.1 nM to 10 μM. Selectivity toward Hg2+ has also been demonstrated in aqueous solutions in the presence of other metal ions. This strategy is simple to utilize and has a low cost and rapid response. The practicability was further investigated by analyzing complex water samples, which suggests its potential for mercury evaluation in environmental samples.
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