Scrolling reduced graphene oxides to induce room temperature magnetism via spatial coupling of defects

Due to its intriguing features and numerous applications, graphene has garnered a lot of interest in recent years. However, it is still very difficult to create graphene-based room-temperature magnets without transition metals or rare earth elements since pristine graphene is inherently diamagnetic due to the delocalized π bonding network. Herein, room-temperature ferromagnetism with a saturation magnetization of 0.93 emu g-1 (300 K) is achieved in defect-rich-reduced graphene oxide (DR-rGO) nanoscrolls by creating a spatial coupling of defects. The experiments and DFT calculations verify that spatial coupling of defects could enhance Rudermann-Kittel-Kasuya-Yosida interactions to induce magnetism in graphene. It displays high-efficiency electromagnetic wave absorption performance with a minimal reflection loss of -62.1 dB and an effective absorption bandwidth of 7.8 GHz (3.0 mm) thanks to greatly improved magnetism. This breakthrough serves as a building block for the creation of room-temperature magnetic carbon materials and expands their applications in many pertinent domains.