Ni‐Based Catalysts for CO2 Methanation: Exploring the Support Role in Structure‐Activity Relationships

Abstract The catalytic hydrogenation of CO 2 to methane is one of the highly researched areas for the production of chemical fuels. The activity of catalyst is largely affected by support type and metal‐support interaction deriving from the special method during catalyst preparation. Hence, we employed a simple solvothermal technique to synthesize Ni‐based catalysts with different supports and studied the support role (CeO 2 , Al 2 O 3 , ZrO 2 , and La 2 O 3 ) on structure‐activity relationships in CO 2 methanation. It is found that catalyst morphology can be altered by only changing the support precursors during synthesis, and therefore their catalytic behaviours were significantly affected. The Ni/Al 2 O 3 with a core‐shell morphology prepared herein exhibited a higher activity than the catalyst prepared with a common wet impregnation method. To have a comprehensive understanding for structure‐activity relationships, advanced characterization (e. g., synchrotron radiation‐based XAS and photoionization mass spectrometry) and in‐situ diffuse reflectance infrared Fourier transform spectroscopy experiments were conducted. This research opens an avenue to further delve into the role of support on morphologies that can greatly enhance catalytic activity during CO 2 methanation.