石墨烯
双金属片
材料科学
电催化剂
化学工程
量子点
金属有机骨架
电化学
催化作用
电解
贵金属
电导率
纳米技术
分解水
电极
无机化学
金属
化学
光催化
冶金
电解质
物理化学
生物化学
工程类
吸附
作者
Hamed Shooshtari Gugtapeh,Milad Rezaei
出处
期刊:ACS applied nano materials
[American Chemical Society]
日期:2024-01-04
卷期号:7 (2): 2086-2099
标识
DOI:10.1021/acsanm.3c05351
摘要
Rational tuning of the electronic structure is one of the feasible routes to enhance the electrical conductivity of electrocatalysts based on metal–organic frameworks (MOFs). Herein, a composite of NiCo-MOF and N-doped graphene quantum dots (NGQDs) with a hierarchical structure was synthesized via a controlled electrodeposition strategy as an exemplary non-noble metal catalyst for alkaline water splitting. The increased active sites by synergy effect between Ni and Co ions and the enhanced local electrical conductivity through uniform incorporation of NGQDs into porous NiCo-MOF matrix offer a catalyst that only demanded overpotentials of 218 and 359 mV to deliver a current density of 100 mA·cm–2 toward the HER and OER, respectively, and also exhibited drastically enhanced electrochemical stability for over 150 h in alkaline media. In particular, the assembled two-electrode setup for overall water electrolysis yields a current density of 10 mA·cm–2 at a low cell voltage of 1.62 V. This facile strategy can provide a creative avenue to design efficient and conductive MOF-based electrocatalysts for large-scale practical applications.
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