纳滤
膜
渗透
基质(水族馆)
溶剂
聚合
图层(电子)
高分子化学
聚酰胺
材料科学
聚四氟乙烯
化学工程
界面聚合
化学
薄膜复合膜
复合数
二甲基甲酰胺
单体
聚合物
复合材料
有机化学
反渗透
生物化学
工程类
地质学
海洋学
渗透
作者
Xinzhu Zhang,Tingyu Li,Zhi Wang,Jixiao Wang,Song Zhao
标识
DOI:10.1016/j.memsci.2022.121294
摘要
The practical application of solvent-resistant nanofiltration (SRNF) still faces major challenges arising from the swelling and dissolution of substrates in organic solvents, especially in polar aprotic solvents such as dimethylformamide (DMF). To address these issues, polytetrafluoroethylene (PTFE) substrates with strong resistance to organic solvents was employed to fabricate solvent-resistant nanofiltration composite membranes. A novel reverse flexible-chain binding interfacial polymerization (rFB-IP) was proposed to fabricate polyamide (PA) selective layer onto PTFE substrate with ultra-low surface energy. Specifically, aiming at strengthening the bonding force between the substrate and selective layer, PDMS was employed as a flexible-chain binder to generate a cross-linked network on the substrate surface and within the pores to generate an interpenetrating structure with PA selective layer. The as-prepared rPA-PDMS/mPTFE composite membrane exhibited DMF permeance of 0.4 L m−2 h−1 bar−1, 97.1% rejection to Rose Bengal (RB), a stable performance during a filtration process for 120 h, or after being immersed in DMF for 120 d. Therefore, the rFB-IP technique successfully settled the issues of the application of PTFE substrate for composite membrane fabrication, and would have outstanding potential in the development of polar aprotic SRNF membrane.
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