Organosulfur Compounds of Allium Subgenus Nectaroscordum Species

Organosulfur compounds formed upon comminuting the bulbs of two Allium subgenus Nectaroscordum species ( Allium siculum and Allium tripedale ) were analyzed by HPLC-PDA-MS/MS. The major organosulfur components were isolated and structurally characterized (MS, NMR), including several previously unknown compounds. It was found that the organosulfur chemistry occurring when these plants are cut is very similar to that observed in onion ( Allium cepa ). In all cases, however, the organosulfur compounds found in Nectaroscordum species were higher homologues of those observed in onion, being formed by various combinations of C 1 and C 4 building blocks derived from methiin and homoisoalliin/butiin, respectively. Thiosulfinates, bis-sulfine, cepaenes, and several cepaene-like compounds were identified among the major organosulfur components present in the homogenized bulbs. Several groups of 3,4-diethylthiolane-based compounds, structurally homologous with onionin A, cepathiolane A, allithiolanes A–H, and cepadithiolactone A, found in onion, were also detected.