热电性
材料科学
压电
铁电性
凝聚态物理
陶瓷
电介质
极化(电化学)
电极
复合材料
抛光
热滞后
体积热力学
相变
热力学
物理
光电子学
量子力学
物理化学
化学
作者
Yu. A. Zakharov,V. P. Sakhnenko,Ivan A. Parinov,I. P. Raevsky,M. A. Bunin,В. А. Чебаненко,M. A. Zaerko,E. I. Sitalo,A. A. Pavelko,Л. И. Киселева
标识
DOI:10.1142/s2010135x20600103
摘要
It has been established that in plates made of hot-pressed ferroelectric ceramics PZT-19 ([Formula: see text]C), after metal electrodes from Ag are burned into opposite surfaces with different depths of mechanical damage, counter-directional stationary deformation gradients and, accordingly, internal electric displacement fields create a stationary flexoelectric effect. As a result, unpolarized ceramics below the Curie temperature become a pyroelectric, and above it become a pyroelectric bolometer. After polishing the less damaged surface and replacing the Ag (valency [Formula: see text]) electrode with Cr ([Formula: see text]) by thermal evaporation in vacuum from the intact surface, a new thermally stable polarization is created, directed from the damaged surface in the interelectrode volume. Such plates have an asymmetric dielectric hysteresis loop, retain the values of the pyroelectric effect and piezoelectric effect in the ferroelectric phase, as well as the bolometric effect in the paraelectric phase after repeated heating cycles to [Formula: see text]C and cooling to [Formula: see text].
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