石墨烯
材料科学
微波食品加热
氧化物
硼
反射损耗
吸收(声学)
兴奋剂
衰减
电磁辐射
光电子学
纳米技术
复合数
复合材料
化学
光学
有机化学
量子力学
物理
冶金
作者
Zhihao Sun,Zhaoqian Yan,Kaicheng Yue,Anran Li,Lei Qian
标识
DOI:10.1016/j.compositesb.2020.108132
摘要
In this work, N/B co-doped reduced graphene oxide were successfully synthesized with two-step hydrothermal self-assembled process, and exhibited excellent electromagnetic microwave absorption under a loading content of only 5 wt%. Its absorption bandwidth below −10 dB was 6 GHz at a thickness of 2.8 mm, and the minimum reflection loss was −52 dB. The nitrogen/boron co-doping mechanism and influences of multiple atomic bonding configurations on the absorbing properties were investigated in detail. The results suggested that various atomic bonding configurations, including C–N bonds (essentially for pyridinic N and pyrrolic N) with electron donor properties and C–N–B bonds with electron acceptor properties, played synergistic role in improving the electromagnetic absorption performance. The equivalent electric diploe composed of various atomic bonding configurations with electronic resonances, consumed the electromagnetic energy in the manner of "molecular" thermal vibration, and endowed the absorber with impedance matching and good electromagnetic attenuation ability.
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