化学
钯
催化作用
碳纤维
选择性
聚苯乙烯
双键
高分子化学
多相催化
树枝状大分子
聚合物
无机化学
有机化学
复合数
材料科学
复合材料
作者
С. А. Грабовский,T. I. Akchurin,В. А. Докичев
标识
DOI:10.2174/1385272824999201202084812
摘要
The results of studies over the past ten years in the field of C=C bond hydrogenation in the presence of palladium catalysts deposited on various inorganic and organic carriers such activated carbons, carbon nanotubes, alumina, zeolites, or composite materials based on Al<sub>2</sub>O<sub>3</sub>-SiO<sub>2</sub>, polystyrene, polypropyleneimine, polyamidoamine and hybrid inorganic/ polymer-carriers, are presented. The selectivity and rates of the hydrogenation process are considered and some comparisons are made. Porous supports and containing dendrimers generally retain palladium particles more effectively. Nanosized palladium stabilized by different dendrimers catalyzes the hydrogenation of C=C bonds in polyfunctional compounds chemoselectively without affecting functional groups, such as CHO, C=O, C(O)OR, CN, NO2, and halogens.
科研通智能强力驱动
Strongly Powered by AbleSci AI