Hydrogen-Bonding Patterns in a Centrosymmetric Structure withZ' = 2: α,α',α''-Trimethyl-1,3,5-benzenetrimethanol

The title molecule, C12H18O3, crystallized in the centrosymmetric space group P2(1)/c with two molecules in the asymmetric unit. Each molecule donates three, and accepts three, hydrogen bonds. The Od...Oa distances in these bonds range from 2.687(3) to 2.787(2) A. The hydroxyl H atoms are ordered. A three-dimensional network of hydrogen-bond chains is formed which is 'decorated' with sets of cyclic hydrogen bonds and numerous finite hydrogen-bond patterns. This structure shows both similarities and differences with respect to the structures of the related molecules benzene-1,3,5-triacetic acid and benzene-1,3,5-trimethanol.