快离子导体
电解质
电池(电)
内阻
材料科学
钠
化学工程
化学
电极
物理化学
冶金
物理
工程类
量子力学
功率(物理)
作者
Jin An Sam Oh,Xiaoyu Xu,Zhihan Zeng,Kexin Wang,Nicholas Yew Jin Tan,Eugene Kok,Jiemin Huang,Lü Li
出处
期刊:Energy & environmental materials
日期:2023-01-02
被引量:1
摘要
The solid‐state electrolyte in a solid‐state battery acts as an electrons' barrier and an ions' bridge between the two electrodes. As solid‐state electrolyte does not store the mobile ions, it is necessary to achieve a thin solid‐state electrolyte to reduce the internal resistance and enhance the energy density. In this work, a thin NASICON solid‐state electrolyte, with a stoichiometry of Na 3 Zr 2 Si 2 PO 12 , is fabricated by the tape‐casting method and its thickness can be easily controlled by the gap between substrate and scraper. The areal‐specific resistance and the flexural strength increase with the electrolyte thickness. A solid‐state sodium metal battery with 86 μm thick Na 3 Zr 2 Si 2 PO 12 exhibits a reversible specific capacity of 73–78 mAh g −1 with a redox potential of 3.4 V at 0.2 C. This work presents the importance of electrolyte thickness to reduce internal resistance and achieve a high energy density for sodium batteries.
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