转鼓
化学
催化作用
基质(水族馆)
卡宾
功能群
组分(热力学)
组合化学
有机化学
作者
Tongxin Liu,Xue Zhu,Shilu Xia,Xin Wang,Pengling Zhang,Guisheng Zhang
标识
DOI:10.1021/acs.orglett.2c01301
摘要
A novel N-heterocyclic carbene-catalyzed three-component umpolung hydroalkylation of [60]fullerene with 4-(chloromethyl)-benzaldehydes/α,β-unsaturated aldehydes and alcohols/thioalcohols has been developed for the flexible and efficient preparation of diverse monoalkylated hydrofullerenes. Organic catalysis, broad substrate scope, excellent functional group tolerance, and products with high diversity and complexity levels are attractive features of this protocol.
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