蜡
材料科学
差示扫描量热法
倾点
流变学
乙烯-醋酸乙烯酯
化学工程
结晶
纳米颗粒
沥青质
Crystal(编程语言)
共聚物
纳米技术
复合材料
聚合物
工程类
物理
程序设计语言
热力学
计算机科学
作者
Xuewen Ning,Xin Song,Sheng Zhang,Yong Wang,Yujun Feng
出处
期刊:ACS omega
[American Chemical Society]
日期:2022-02-14
卷期号:7 (7): 5853-5863
被引量:7
标识
DOI:10.1021/acsomega.1c05953
摘要
Nanohybrid materials can significantly inhibit wax deposition and improve the fluidity of crude oil. However, the mechanisms behind wax resolving, crystal modification, and flow improving are still unclear owing to the complexity of crude oil. Here, we compared the effect of ethylene vinyl acetate (EVA) and nanohybrids composed of EVA and SiO2 nanoparticles on wax crystallization and rheological behavior of Shengli waxy oil. Differential scanning calorimetry results indicate that SiO2 nanoparticles boost the efficiency of EVA for reducing the wax appearance temperature of waxy crude oil. Thermo X-ray diffraction characterization demonstrates that EVA/SiO2 nanohybrids cut down the crystal index of waxes, with the grain size of crystal cells decreased in (006) and (200) but increased in (110) cross sections. Polarized optical microscopy imaging reveals that EVA can modify the morphology of wax crystals to suppress the formation of wax gel, and nanohybrids serve as nucleuses to adsorb asphaltenes and resins, restraining the appearance of wax crystals. The rheological test shows that nanohybrids outperform EVA in decreasing the viscosity, inflection point, and yield stress of waxy crude oil. These findings help the understanding of flow improving by nanohybrid materials and offer guidelines for designing the new generation of wax inhibitors for safe transportation and flow assurance of waxy crude oil.
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