Abstract Complexes of Cu(I) with pyridine, picolines, lutidines, quinolines, piperidine and acridine have been studied by potentiometric method. Only the complexes 3 picoline, 2.4 and 2.6 lutidines, quinoline, piperidine and acridine could be isolated in pure form. The elementary analyses and the infra red spectra of the 1:1 complexes suggest that they behave like pyridine complexes and the increase in γ(CH ring) contributes most to NM bond strength.