化学
分子内力
亚胺
立体化学
分子内反应
药物化学
有机化学
催化作用
作者
Latchezar S. Trifonov,A. S. Orahovats
标识
DOI:10.1002/hlca.19870700130
摘要
Abstract Allenic acids are found to add to dicyclohexylcarbodiimide affording, in the presence of Et 2 NH, the 4 H ‐1,3‐oxazin‐4‐ones 5 via 4 . Under neutral conditions, they add to diaryl‐ or pyridyl(cyclohexyl)carbodiimides and triphenylketene imine to give the corresponding tricyclo[5.2.2.0 1,5 ]undeca‐4,8,10‐trien‐3‐ones 7 , 8 , 9 , and 12 . The allenic phenyl ester 13a dimerises, on heating in a [2+2] head‐to‐head fashion, to 14 but fails to undergo intramolecular Diels ‐ Alder cyclization, to 15 .
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