Electric field controlled formation and dissociation of multiwalled carbon nanotube conductive pathways in a polymer melt

Electric field controlled formation and dissociation of multiwalled carbon nanotube (MWCNT) conductive pathways in a polycarbonate (PC) melt are investigated by the dynamic percolation measurement. The results show that field-induced MWCNT alignment causes the decrease in the activation energy of conductive pathway formation. The directional or disordered alignment of MWCNTs in the PC melt results in the transition from a conductor to an insulator as the electric field changes from 500 to 1 V/cm. This electric-controllable directional or disordered alignment technology is promising for the fabrication of low-dimensional conductive materials and applications of voltage-switch devices.