结晶度
材料科学
钙钛矿(结构)
带隙
光电流
成核
光伏系统
能量转换效率
粒度
化学工程
光电子学
制作
纳米技术
化学
冶金
复合材料
有机化学
生态学
替代医学
病理
工程类
生物
医学
作者
Kantapa Yolthida,Dang Xuan Long,Yoon Hee Jang,Jongin Hong
出处
期刊:ACS applied energy materials
[American Chemical Society]
日期:2023-12-06
卷期号:6 (24): 12285-12295
被引量:1
标识
DOI:10.1021/acsaem.3c01808
摘要
Low-bandgap Pb–Sn mixed perovskite solar cells (PSCs) are emerging as promising contenders for next-generation solar technology due to their broad spectral response and high photocurrent output. To achieve high-quality perovskite films, we propose a mixed antisolvent engineering approach for Pb–Sn mixed perovskites. This technique balances the saturation rate between the precursor and the mixed antisolvent, modulating perovskite nucleation and crystal growth. We discovered that an optimal mixture of chlorobenzene (CB) and ethyl acetate (EA) decelerated the extraction of perovskite precursors, leading to the formation of smoother perovskite films with improved crystallinity and larger grain sizes. Consequently, we observed enhanced charge transport, reduced trap state densities, and an extended near-infrared (NIR) response. These enhancements collectively contributed to the improved performance of low-bandgap Pb–Sn mixed PSCs. Furthermore, the use of EA, an eco-friendly antisolvent, aligns our approach with sustainable manufacturing practices by reducing toxicity during fabrication.
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