三聚氰胺
吸附
吸附剂
共晶体系
材料科学
化学工程
薄荷醇
环境友好型
选择性
多孔性
化学
吸附
有机化学
微观结构
复合材料
工程类
生态学
生物
催化作用
作者
Patrycja Makoś-Chełstowska,Edyta Słupek,Aleksandra Mielewczyk‐Gryń,Tomasz Klimczuk
出处
期刊:Chemosphere
[Elsevier]
日期:2024-01-01
卷期号:346: 140533-140533
标识
DOI:10.1016/j.chemosphere.2023.140533
摘要
This paper proposes the preparation of a new sorbent material based on melamine sponges (MS) with superhydrophobic, superoleophilic, and magnetic properties. This study involved impregnating the surface of commercially available MS with eco-friendly deep eutectic solvents (DES) and Fe3O4 nanoparticles. The DES selection was based on the screening of 105 eutectic mixtures using COSMO-RS modeling. Other parameters affecting the efficiency and selectivity of oil removal from water were optimized using the Box-Bhenken model. Menthol:Thymol (1:1)@Fe3O4-MS exhibited the highest sorption capacity for real crude oils (101.7–127.3 g/g). This new sponge demonstrated paramagnetic behavior (31.06 emu/g), superhydrophobicity (151°), superoleophobicity (0°), low density (15.6 mg/cm3), high porosity (99 %), and excellent mechanical stability. Furthermore, it allows multiple regeneration processes without losing its sorption capacity. Based on these benefits, Menthol:Thymol (1:1)@Fe3O4-MS shows promise as an efficient, cost-effective, and eco-friendly substitute for the existing sorbents.
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