Advancing Catalysts by Stacking Fault Defects for Enhanced Hydrogen Production: A Review

Abstract Green hydrogen, derived from water splitting powered by renewable energy such as solar and wind energy, provides a zero‐emission solution crucial for revolutionizing hydrogen production and decarbonizing industries. Catalysts, particularly those utilizing defect engineering involving the strategical introduction of atomic‐level imperfections, play a vital role in reducing energy requirements and enabling a more sustainable transition toward a hydrogen‐based economy. Stacking fault (SF) defects play an important role in enhancing the electrocatalytic processes by reshaping surface reactivity, increasing active sites, improving reactants/product diffusion, and regulating electronic structure due to their dense generation ability and profound impact on catalyst properties. This review explores SF in metal‐based materials, covering synthetic methods for the intentional introduction of SF and their applications in hydrogen production, including oxygen evolution reaction, photo‐ and electrocatalytic hydrogen evolution reaction, overall water splitting, and various other electrocatalytic processes such as oxygen reduction reaction, nitrate reduction reaction, and carbon dioxide reduction reaction. Finally, this review addresses the challenges associated with SF‐based catalysts, emphasizing the importance of a detailed understanding of the properties of SF‐based catalysts to optimize their electrocatalytic performance. It provides a comprehensive overview of their various applications in electrocatalytic processes, providing valuable insights for advancing sustainable energy technologies.