Enantioselective Synthesis of Alkyl Allyl Ethers via Palladium‐Catalyzed Redox‐Relay Heck Alkenylation of O‐Alkyl Enol Ethers

Abstract Herein we report a transformation that generates an array of enantiomerically enriched, alkyl allyl ethers. Cyclic, acyclic, and heteroatom‐bearing alkenyl triflates undergo an enantioselective, palladium‐catalyzed C−C bond formation with diverse acyclic O ‐alkyl enol ethers in good yields and excellent enantioselectivities.