Broadband Short-Wave Infrared Light-Emitting Diodes Based on Cr3+-Doped LiScGeO4 Phosphor

Short-wave infrared (SWIR) spectroscopy has recently emerged as an important technology across a wide range of areas, whether industrial, biomedical, or environmental. Nevertheless, it is still a long-standing challenge to develop robust SWIR light sources. The SWIR phosphor-convert light emitting diodes (LEDs) by coating blue LED chips with desirable SWIR-emitting phosphors are becoming an ideal alternative for solid-state SWIR light sources due to its compactness, low-cost, and long operating lifetime, as does the commercial white LEDs. Herein, we report a blue-pumped Cr³⁺-doped LiScGeO₄ SWIR phosphor as a luminescent converter for phosphor-convert SWIR LEDs. This phosphor shows an intense SWIR emission band with a peak wavelength at ∼1120 nm owing to the ⁴T₂ → ⁴A₂ electron transition of Cr³⁺ when exciting with blue light. The full width at half-maximum (fwhm) of the phosphor is ∼300 nm and the absolute quantum efficiency is determined to be ∼26%. SWIR LED prototypes are constructed by combining the optimized phosphor materials with commercial blue InGaN LED chips, which can generate a commendable emission band in the SWIR region over 800-1600 nm and achieve a maximum output power of ∼4.78 mW at 60 mA with the photoconversion efficiency of 4.4%. The current exploration of Cr³⁺-doped SWIR-emitting phosphors will lay the foundation to engineer phosphor-convert SWIR LEDs for applications in night-vision surveillance and SWIR spectroscopy technology. These blue-light-excitable SWIR-emitting phosphors can serve as an important complement to the spectral gap of the current Cr³⁺-doped phosphors in the SWIR region and will pave the way toward cost-effective phosphor-converted solid-state SWIR light sources.