碳硼烷
反应性(心理学)
化学
碳基
群(周期表)
主组元素
硼
位阻效应
团簇化学
硼烷
碳纤维
组合化学
立体化学
有机化学
分子
材料科学
过渡金属
催化作用
替代医学
复合材料
病理
复合数
医学
标识
DOI:10.1016/j.cclet.2021.12.016
摘要
Carboranes are a class of polyhedral boron-carbon molecular clusters, they can serve as versatile ligands in stabilizing low-valent main group element compounds, due to their exceptionally thermal and chemical stabilities, easy modifications at the cage carbon vertices, as well as large spherical steric effects. These carborane-based ligands provide interesting opportunities for the synthesis of low-valent main group element compounds with novel structure and reactivity, which indeed enrich the chemistry of low-valent element main group compounds. This review summarizes the recent advances in the chemistry of low-valent group 13 and group 14 element compounds supported by carborane-based ligands. Achievements and perspectives in this new and flourishing field are discussed in this review. A review of recent achievements on carborane-based ligands in low-valent group 13 and group 14 elements chemistry, mainly focus on their synthesis, structure and reactivity.
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