The content of total sugar,sucrose,fructose and protein in the leaves of 3-yr.-old Betula platyphylla was measured after the treatment by three exogenous sugar solutions(sucrose,fructose,glucose) and three high concentrations of CO2(700,1400,2100μL·L^-1) for about a month in 1998.The results showed that spraying three exogenous sugar solutions increased markedly the content of sugar and protein of leaves under 700μL·L^-1 and 1400μL·L^-1 CO2.The effect of spraying exogenous sucrose solution was the best among the three exogenous sugars.The treatment of spraying exogenous sugar solution and 2100μL·L^-1 CO2 constrained the accumulation of total sugar and protein of leaves.There was no difference in protein content of leaves when spraying glucose and fructose solutions under 700μL·L^-1 and 1400μL·L^-1 CO2.The treatrnent of 2100μL·L^-1 CO2 concentration significantly increased the contents of total sugar,sucrose,fructose,and protein of leaves compared with that of the 700μL·L^-1 and 1400μL·L^-1 CO2 except the plants spraying fructose solution.there was positive correlation between the content of sugar of leaves and CO2 concentration when spraying same exogenous sugar solution.