碱性燃料电池
燃料电池
氢氧化物
膜
离子交换
氢氧化钾
离子电导率
碳化作用
氢氧化钠
化学
化学工程
无机化学
材料科学
离子
工程类
电极
电解质
有机化学
物理化学
生物化学
作者
Christopher G. Arges,Le Zhang
出处
期刊:ACS applied energy materials
[American Chemical Society]
日期:2018-06-15
卷期号:1 (7): 2991-3012
被引量:206
标识
DOI:10.1021/acsaem.8b00387
摘要
The development of alkaline fuel cells over the past decade has led to exciting developments in low resistant and alkaline stable anion exchange membranes (AEMs). This Review highlights new material chemistries and macromolecular designs that have fueled AEMs with ionic conductivities greater than 100 mS cm–1, while demonstrating stability for extended periods in base bath solutions of 1 M potassium (or sodium) hydroxide solutions at temperature of 80 °C or greater. The new AEMs have led to AEM fuel cells (AEMFCs) with power density values that exceed 1 W cm–2 with hydrogen and oxygen. AEM research activities are motivated in large part by their prospect to realize fuel cells free of platinum group metals, which is paramount for cost reduction of fuel cell technology. In addition to highlighting the remarkable achievements of AEMs in the past 4 years, this Review discusses future priorities for the scientific community to address in AEM development. These priorities include stability and conductivity under low humidity or dry conditions, resisting carbonation and oxidation, and AEMFC device stability studies.
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